Atomic Term Symbols
Applying the 'definition' of the term symbol:
results in a 2S1/2 atomic term for the ground state of the H atom.
Exciting the single hydrogenic electron to higher orbitals results in different atomic states or 'terms' of the atom. Note that an H atom with the electron in a 3d and 10d orbital both result in 2D3/2 and 2D5/2 terms, but at different energies.
The lowest electron configuration of He is 1s2.
The ground state of the neutral helium atom is therefore
1S0
In fact, any electron configuration (orbital population) that consists of
any combination of closed shells or subshells will result in this
(totally symmetric 1S0 term.
Therefore, in the designation of atomic terms, the contribution from closed subshell
electrons may be neglected.
He(1s2)
Ground state term symbol
is 1S0
He(1s12s1) An Excited State Configuration
Terms:
1S0
,
3S1
{
There is no
3S0
Nor
3S-1
Term
}
B(1s22s22p1)
Term symbol:
2P1/2,
2P3/2
The spin orbit splitting is
regular so 2P1/2. is the ground state.
C(1s22s22p2)
Calculate the number of possible electron arrangements in the given
configuration
There are 6!/4!2! = 15 microstates expected
Write down all these possibilities
Decompose this table into terms
What are the atomic state term symbols resulting from the lowest energy configuration of N
(1s2 2s2 2p3) ?
This configuration has 6!/3!3! = 20 microstates
Draw all the possibilities
Tabulate the totals
Assign Terms
What are the atomic state term symbols resulting from the
lowest energy configuration of O
(1s2 2s2 2p4) ?
Aha! We don't haver to do this because the terms arising from p2
and p4 are exactly the same.
Note however the ordering of the J levels is now inverted
Check this with reality
The terms resulting from a single open subshell are tabulated below for your amusement.